T.A. Hendriks (Ron)

PhD Candidate / PhD Student


Title: Controlled fabrication of electrode/electrolyte nanocomposites through self-assembly for enhanced interfacial properties for lithium diffusion, for 3D solid-state batteries.

Currently, lithium-ion batteries are the most popular rechargeable batteries. However, most commercial rechargeable lithium-ion batteries deliver energy densities of only 10-15% of their theoretical values1,2. Limitations are the slow electrode process kinetics, low ionic diffusion and low electronic conductivity, especially at the electrode-electrolyte interfaces. Gaining control over the interface is a grand challenge and is believed to be even more important than designing new electrode and electrolyte materials3.

Figure 1. Ragone Plot of Solid-State Battery designs, 2D planar and 3D nanocomposite

This research is to realize self-assembled 3D solid-state batteries with improved energy densities through controlled electrode-electrolyte interface engineering. Enhanced interfacial properties for lithium diffusion can be achieved through studying and exploiting the nano-architecting of 3D electrode-electrolyte structures to control the individual crystal structures in the nanocomposites.

Figure 2. Self-assembled nanocomposite of a perovskite (BiFeO3) and spinel (CoFe2O4). Adapted from:4,5

The realization of such electrode-electrolyte nanocomposites, through self-assembly from two immiscible oxide materials, will provide a simple and low cost fabrication process. This will enable the direct transfer from small lab-scale devices to large industry-scale battery applications.

1  F. Cheng, J. Liang, Z. Tao, and J. Chen, Adv. Mater. 23, 1695-1715 ( 2011),DOI: 10.1002/adma.201003587

2  J.F.M. Oudenhoven, R.J. Vullers, and R. van Schaijk, Int. J. Energy Res. 36, 1139 (2012), DOI: 10.1002/er.2949

3  J.-M. Tarascon, and M. Armand, Nature 414, 359 (2001), DOI: 10.1038/35104644

4  H. Zheng, et. al., Adv. Mater. 18, 2747 – 2752 (2006), DOI: 10.1002/adma.200601215

5  H. Zheng, et. al. Nano Lett. 6, 1401 – 1407 (2006), DOI: 10.1021/nl060401y

PhD: Ron Hendriks

Supervisor: Mark Huijben




Recent Articles
M. Cunha, D., Hendriks, T. A., Vos, C. M., Singh, D. P., & Huijben, M. (2017). Nanoscale mapping of electrochemistry for enhanced solid state batteries. Poster session presented at MESA+ Meeting 2017, Enschede, Netherlands.
Hendriks, T. A., Monteiro Cunha, D., Singh, D. P., & Huijben, M. (2016). Electrochemical properties of single-crystalline LiMn2O4 cathode thin-films. -. Poster session presented at 18th International meeting on Li. Bat. IMLB, Chicago, Illinois, USA, .

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University of Twente
Faculty of Science and Technology
Carré  3223
P.O. Box 217
7500 AE Enschede
The Netherlands