prof.dr. J. Lange (Jean-Paul)

Principal research chemist at Shell Technology and Professor in Chemical biorefining at the University of Twente.
25 years of “discovery” research in industry on catalytic processes for manufacturing fuels and chemicals from fossil and renewable feedstocks.

PROFESSIONAL HISTORY & EDUCATION

Academic Research (2012 – today)University of Twente, Enschede, the Netherlands, Professor in Chemical Biorefining (2012 – today)
Industrial Research (1989 – today)Shell Technology Centre, Amsterdam, the NetherlandsPrincipal research chemist (2006 - today)Senior research chemist (1996 - 2006)Research chemist (1992 - 1996)Associate research chemist (1989 - 1992)
Post-Doc. (1987 – 1988)Lehigh University, Bethlehem (PA), USASupervisor: Prof. K. Klier
PhD. (1983 – 1987)Doktor der NaturwissenschaftenFritz-Haber-Institut der Max Planck Gesellschaft, Berlin, Germany Supervisor: Dr. H.G. KargeThesis: “Study of the deposition of coke onto Mordenite catalysts during the reaction with ethene” (in German)
Chem.Trainee (Aug. 1983)Zschimmer & Schwarz GmbH, Lahnstein, Germany
Graduation (1979 – 1983)Licencié en Sciences chimiques Université Notre-Dame de la Paix, Namur, Belgium Supervisor: Dr. J. B.NagyThesis: “Physicochemical properties of ZSM-5 and Mordenite zeolites exchanged with cesium: adsorption and reactivity of isopropanol” (in French)

COMPETENCIES

Technology

Applied heterogeneous catalysis for manufacturing fuels and chemicals, e.g. methane conversion, synthesis gas technologies, oil refining, petrochemicals manufacture, manufacture of bio-based fuels and bio-based chemicals
Spectroscopy on catalyst and adsorbates (including in situ)
Chemical engineering of catalytic processes, incl. reactor design, flow-sheeting, conceptual process design and manufacturing economics

Liquefaction

Oils

Acids

Reaction Yield

Catalysis

Liquefaction

Industry

Catalysis

Xylose

Faculty of Science and Technology (TNW), Sustainable Process Technology (SPT)

Ricciardi, L. , Verboom, W. , Lange, J. P. , & Huskens, J. (2022). Production of furans from C₅and C₆sugars in the presence of polar organic solvents. Sustainable Energy and Fuels, 6(1), 11-28. https://doi.org/10.1039/d1se01572a

Ricciardi, L. , Verboom, W. , Lange, J. P. , & Huskens, J. (2021). Selectivity switch by phase switch-the key to a high-yield furfural process. Green chemistry, 23(20), 8079-8088. https://doi.org/10.1039/d1gc01752g

Te Molder, T. D. J. , Kersten, S. R. A. , Lange, J. P. , & Ruiz, M. P. (2021). From Woody Biomass to Ethylene Glycol: Inorganics Removal Boosts the Yield. Industrial and engineering chemistry research, 60(37), 13515-13522. https://doi.org/10.1021/acs.iecr.1c02353

Ricciardi, L. (2021). Furfural Manufacture from Xylose: Routes towards High Selectivity and Novel Processes. University of Twente. https://doi.org/10.3990/1.9789036552592

Lange, J. P. (2021). Towards circular carbo-chemicals-the metamorphosis of petrochemicals. Energy and Environmental Science, 14(8), 4358-4376. https://doi.org/10.1039/d1ee00532d

te Molder, T. D. J. , Kersten, S. R. A. , Lange, J. P. , & Ruiz, M. P. (2021). Cellulosic glycols: an integrated process concept for lignocellulose pretreatment and hydrogenolysis. Biofuels, Bioproducts and Biorefining, 15(6), 1725-1736. https://doi.org/10.1002/bbb.2269

Lange, J. P. (2021). Author Correction: Performance metrics for sustainable catalysis in industry (Nature Catalysis, (2021), 4, 3, (186-192), 10.1038/s41929-021-00585-2). Nature Catalysis, 4(6), 532. https://doi.org/10.1038/s41929-021-00634-w

Ricciardi, L. , Verboom, W. , Lange, J. P. , & Huskens, J. (2021). Selective Extraction of Xylose from Acidic Hydrolysate-from Fundamentals to Process. ACS Sustainable Chemistry and Engineering, 9(19), 6632-6638. https://doi.org/10.1021/acssuschemeng.1c00167

Te Molder, T. D. J. , Kersten, S. R. A. , Lange, J. P. , & Ruiz, M. P. (2021). Ethylene Glycol from Lignocellulosic Biomass: Impact of Lignin on Catalytic Hydrogenolysis. Industrial and engineering chemistry research, 60(19), 7043-7049. https://doi.org/10.1021/acs.iecr.1c01063

Lange, J-P. (2021). Performance metrics for sustainable catalysis in industry. Nature Catalysis, 4(3), 186-192. https://doi.org/10.1038/s41929-021-00585-2

PUBLICATIONS SORTED BY RESEARCH AREA

Incl. 5 book chapters (with *)

Biofuels and bio-based chemicals

47. Liquefaction of Lignocellulose in Fluid Catalytic Cracker Feed: A Process Concept Study
S. Kumar, J.-P. Lange, G. van Rossum, S.R.A. Kersten;
ChemSusChem 2015, 8, 4086-4094 (DOI)
46. Renewable Feedstocks: The Problem of Catalyst Deactivation and its Mitigation
J.-P. Lange; Angew. Chem. Int. Ed. 2015, 54, 13186–13197 (DOI)
45. Liquefaction of lignocellulose in fractionated light bio-oil: Proof of concept and techno-economic assessment
S. Kumar, J.-P. Lange, G. van Rossum, S.R.A. Kersten; ACS Sustainable Chemistry & Engineering 2015, 3, 2271-2280 (DOI)
44. Bio-oil fractionation by temperature-swing extraction: Principle and application
S. Kumar, J.-P. Lange, G. Van Rossum, S.R.A. Kersten; Biomass and Bioenergy 2015, 83, 96-104 (DOI)
43. A new approach for bio-oil characterization based on gel permeation chromatography preparative fractionation
M. Castellví Barnés, J.-P. Lange, G. van Rossum, S.R.A. Kersten, J. Anal. Appl. Pyrol. 2015, 113, 444–453 (DOI)
42. Liquefaction of lignocellulose: Do basic and acidic additives help out?
S. Kumar, J.-P. Lange, G. van Rossum, S. Kersten, Chem. Eng. J. 2015, 278, 99-104 (DOI)
41. Document Liquefaction of lignocellulose: Process parameter study to minimize heavy ends
Kumar, S., Lange, J.-P., Van Rossum, G., Kersten, S.R.A., Industrial and Engineering Chemistry Research 2014, 53 (29), 11668-11676 (DOI)
40. Liquefaction of Lignocellulosic Biomass: Solvent, Process Parameter, and Recycle Oil Screening
G. van Rossum, W. Zhao, M. Castellvi Barnes, J.-P. Lange, S.R.A. Kersten, ChemSusChem 2014, 7(1), 253-259 (DOI)
39. Furfural Production by ‘Acidic Steam Stripping’ of Lignocellulose
J. van Buijtenen, J.-P. Lange, L. Espinosa Alonso, W. Spiering, R. F. Polmans, R. J. Haan, ChemSusChem 2013, 6, 2132-2136 (DOI)
38. Furfural – a promising platform for lignocellulosic biofuels
J.-P. Lange, E. van der Heide, J. van Buijtenen, R.J. Price, ChemSusChem 2012, 5, 150-166 (DOI)
37. Valeric biofuels: a platform of cellulosic transportation fuels
J.-P. Lange, R. Price, P.M. Ayoub, J. Louis, L. Petrus, L. Clarke, J. Gosselink, Angew. Chem. Int. Ed., 2010, 49, 4479-4483 (DOI)
36^*. Cellulosic Biofuels – a sustainable option for transportation
J.-P. Lange, I. Lewandowski, P. Ayoub, in “Sustainable Development in the Process Industry – cases and impacts”, (Harmsen, Powell, eds) Wiley, 2010, 171-208 (DOI)
35. Conversion of Furfuryl Alcohol into Ethyl Levulinate using Solid Acid Catalysts
J.-P. Lange, W.D. van de Graaf, and R.J. Haan, ChemSusChem 2009, 2, 437-441 (DOI)
34. Cellulosic biofuels – a short introduction to manufacture and economics
J.-P. Lange, 15th Eur. Biomass conf. & Exhibition, Berlin, 7-11 May 2007, 1884-1886 (DOI)
33. Lignocellulose conversion: an introduction to chemistry, process and economics
J.-P. Lange, Biofuels, Bioprod. Bioref., 2007, 1, 39-48 (DOI)
32. Towards ‘bio-based’ nylon: conversion of γ-valerolactone to methyl pentenoate under catalytic distillation conditions
J.-P. Lange, J.Z. Vestering, R.J. Haan, Chem. Commun., 2007, 3488-3490 (DOI)
31^*. Lignocellulose conversion: an introduction to chemistry, process and economics
J.-P. Lange, in ‘Catalysis for Renewables: from feedstock to energy production’ (eds. G. Centi and R.A. van Santen) Wiley-VCH, Weinheim, 2007, 238(1), 21-51 (DOI)

Chemical Manufacture

30^*. Resource efficiency of chemical manufacturing chains – present and future
J.-P. Lange, in “Sustainable Development in the Process Industry – cases and impacts”, (Harmsen, Powell, eds) Wiley, 2010, 23-38 (DOI)
29. Sustainable Chemical Manufacturing: A Matter of Resources, Wastes, Hazards, and Costs.
Lange, J.-P., ChemSusChem 2009, 2, 587-592 (DOI)
28^*. Propylene epoxidation via Shell’s SMPO process: 30 years of research and operation
J.K.F. Buijink, J.-P. Lange, A.N.R. Bos, A.D. Horton, F.G.M. Niele, in ‘Mechanism in homogeneous and heterogeneous epoxidation catalysis’ (ed. S.T. Oyama) Elsevier, Amsterdam, 2008, 355-371 (DOI)
27. Shell’s styrene monomer and propylene oxide (SMPO) process: Lessons learnt from 28 years of highly selective catalytic propylene epoxidation
J.K.F. Buijink, J.-P. Lange, A.N.R. Bos, A.D. Horton, F.G.M. Niele, Prep. Pap.-Am. Chem. Soc., Div. Petr. Chem., 2007, 52 (2), 229-232 (DOI)
26. Dehydration of phenyl-ethanol to styrene under reactive distillation conditions: understanding the catalyst deactivation
J.-P. Lange, V. Otten, Ind. Eng. Chem. Res., 2007, 46, 6899-6903 (DOI)
25. A novel reverse flow reactor with integrated separation
A.N.R. Bos, J.-P. Lange, G. Kabra, Chem. Eng. Sci. 2007, 62, 5661-5662 (DOI)
24. Dehydration of phenyl-ethanol to styrene: zeolite catalysts operating under reactive distillation
J.-P. Lange, V. Otten, J. Catal., 2006, 238(1), 6-12 (DOI)
23. Oxycracking of hydrocarbons: chemistry technology and economic potential
J.-P. Lange, R.J. Schoonebeek, P.G.D.L. Mercera, F.W. van Breukelen, Appl. Catal. A: General, 2005, 283, 243-253 (DOI)
22. Monolithic catalysts for the fixed-bed hydrogenation of polymers
J.-P. Lange, L. Schoon, A. Villena, W. de Jong, Chem. Comm., 2004, 2864-2865 (DOI)
21. Sustainable development: efficiency and recycling in chemicals manufacturing
J.-P. Lange, Green Chem., 2002, 4(6), 546-550 (DOI)
20. Catalytic rearrangement of aliphatic hydroperoxides
J.-P. Lange, A.J.M. Breed, Cat. Comm., 2002, 3, 25-28 (DOI)
19. Solid acid catalysts for converting alkenes and alkanols to carboxylic acids
J.-P. Lange, L. Petrus, Appl. Catal. A: General, 2001, 216, 285-294 (DOI)
18. Mass transfer limitations in zeolite catalysts: the dehydration of 1-phenyl-ethanol to styrene
J.-P. Lange, C.M.A.M. Mesters, Appl. Catal. A: General, 2001, 210, 247-255 (DOI)
17. Fuels and chemicals manufacturing: guidelines for understanding and minimising the production costs
J.-P. Lange, CatTech, 2001, 5(2), 82-95 (DOI)
16. Catalysis research for improved process economics
J.-P. Lange, CatTech, 1999, 3(1), 51-52

Natural gas conversion to fuels and chemicals

15^*. Economics of alkane conversion
J.-P. Lange, in ‘Sustainable strategies for the upgrading of natural gas: fundamentals, challenges and opportunities’ (E.G. Derouane et al., eds) Kluwer 2005, pp. 51-83 (DOI)
14. Methanol synthesis: a short review of technology improvements
J.-P. Lange, Catal. Today, 2001, 64, 3-8 (DOI)
13. Perspectives for manufacturing methanol at fuel value
J.-P. Lange, Ind. Eng. Chem. Res., 1997, 36(10), 4282-4290 (DOI)
12. Processes for Converting Methane to liquid Fuels: Economic Screening through Energy Management
J.-P. Lange, P.J.A. Tijm, Chem. Eng. Sci., 1996, 51, 2379-2387 (DOI)
11. Keys to methane conversion technologies
J.-P. Lange, K.P. de Jong, J. Ansorge, P.J.A. Tijm, Studies in Surf. Sci. and Catal. 107, (1997), 81-86 (DOI)
10. Conversion of Methane to Liquid Fuels and Bulk Chemicals. II. Indirect dehydrogenation routes
J.-P. Lange, Chimie Nouvelle, 1995, 13, 1433-1436 (DOI)
09. Conversion of Methane to Liquid Fuels and Bulk Chemicals. I. Direct dehydrogenation routes
J.-P. Lange, Chimie Nouvelle, 1994, 12, 1403-1406 (DOI)

In-situ Spectroscopy in Catalysis

08. U.v.-vis-n.i.r. studies of Fe(II)-A zeolite
J.-P. Lange, K. Klier, Zeolites, 1994, 14, 462-468 (DOI)
07. Coke Formation through the reaction of ethene over hydrogen mordenite. III. IR and 13C-NMR studies
J.-P. Lange, A. Gutsze, J. Allgeier, Appl. Catal., 1988, 45, 345-356 (DOI)
06. Coke Formation through the reaction of olefins over hydrogen mordenite. II. In situ EPR measurements under on-stream conditions
H.G. Karge, J.-P. Lange, A. Gutsze, M. Laniecki, J. Catal., 1988, 114, 144-152 (DOI)
05. Coke Formation through the reaction of olefins over hydrogen mordenite. I. EPR measurements under static conditions (DOI)
J.-P. Lange, A. Gutsze, H.G. Karge, J. Catal., 1988, 114, 136-143
04. Carbonisation of polyethylene over acidic zeolites
A. Gutsze, J.-P. Lange, H.G. Karge, J. Allgeier, J. Catal. 1988, 113, 525-528 (DOI)
03. Oligomerization and coke formation on zeolites studied by ESR
A. Gutsze, H. Karge, J.P. Lange, Ser. Fiz. (Uniw. im. Adama Mickiewicza Poznaniu) 1985, 54 (Radio Microwave Spectrosc.), 119
02. Studies on coke formation on dealuminated mordenites by in-situ IR and EPR measurements
H.G. Karge, E.P. Boldingh, J.-P. Lange, A. Gutsze, Acta Phys. Chem. 1985, 31 (1-2), 636-648
01. Reactivity of isopropanol on K- and Cs-exchanged ZSM-5 and mordenite
B.Nagy, J., Lange, J.-P., Gourgue, A., Bodart, P., Gabelica, Z., in "Catalysis by acid and bases" (eds. B. Imelik et al.), Elsevier (1985), p. 127-134 (DOI)