ing. R.J.M. Egberink (Richard)

Chemistry

# Actinoid Atom
# Complexation
# Diluting Agent
# Ligand
# Nitric Acid

Engineering & Materials Science

# Actinides
# Ligands
# Nitric Acid

Faculty of Science and Technology (TNW), Molecular Nanofabrication (MNF)

Verlinden, B., Wilden, A., Van Hecke, K. , J. M. Egberink, R. , Huskens, J. , Verboom, W., Hupert, M., Weßling, P., Geist, A., Panak, P. J., Hermans, R., Verwerft, M., Modolo, G., Binnemans, K., & Cardinaels, T. (2023). Solvent Optimization Studies for a New EURO-GANEX Process with 2,2’-Oxybis(N,N-di-n-decylpropanamide) (mTDDGA) and Its Radiolysis Products. Solvent extraction and ion exchange, 41(1), 59-87. https://doi.org/10.1080/07366299.2022.2125151

Karak, A., Mahanty, B., Mohapatra, P. K. , Egberink, R. J. M., Valsala, T. P., Sathe, D. B., Bhatt, R. B. , Huskens, J. , & Verboom, W. (2023). Highly selective carrier mediated transport of plutonium(IV) across a supported liquid membrane using two substituted tripodal amides. Separation Science and Technology (Philadelphia), 58(2), 382-393. https://doi.org/10.1080/01496395.2022.2119411

Gujar, R. B., Verma, P. K., Mahanty, B., Bhattacharyya, A., Ali, S. M. , Egberink, R. J. M. , Huskens, J. , Verboom, W., & Mohapatra, P. K. (2023). Sequestration of Np⁴⁺ and NpO₂²⁺ ions by using diglycolamide-functionalized azacrown ethers in C₈mim·NTf₂ ionic liquid: Extraction, spectroscopic, electrochemical and DFT studies. Journal of molecular liquids, 370, [120872]. https://doi.org/10.1016/j.molliq.2022.120872

Verlinden, B., Van Hecke, K., Wilden, A., Hupert, M., Santiago-Schübel, B. , Egberink, R. J. M. , Verboom, W., Kowalski, P. M., Modolo, G., Verwerft, M., Binnemans, K., & Cardinaels, T. (2022). Gamma radiolytic stability of the novel modified diglycolamide 2,2′-oxybis(N,N-didecylpropanamide) (mTDDGA) for grouped actinide extraction. RSC advances, 12(20), 12416-12426. https://doi.org/10.1039/d1ra08761d

Bhattacharyya, A., Kanekar, A. S. , Egberink, R. J. M. , Verboom, W. , Huskens, J., & Mohapatra, P. K. (2022). Unique selectivity reversal between Am³⁺ and Eu³⁺ ions by incorporation of alkyl branching in diglycolamide derivatives: DFT validation of experimental results. New journal of chemistry, 46(38), 18543-18550. https://doi.org/10.1039/d2nj03007a

Karak, A., Mahanty, B., Mohapatra, P. K., Musharaf Ali, S. , Egberink, R. J. M., Sathe, D. B., Bhatt, R. B., Valsala, T. P. , Huskens, J. , & Verboom, W. (2022). Role of ligand spacer length of a tripodal amide on uranium(vi) and plutonium(iv) complexation: synthesis, solvent extraction, liquid membrane transport and theoretical studies. New journal of chemistry, 46(44), [21221-21228]. https://doi.org/10.1039/d2nj03354b

Verma, P. K., Karak, A., Sahu, P., Aswal, V. K., Mahanty, B., Ali, S. M. , Egberink, R. J. M. , Huskens, J. , Verboom, W., & Mohapatra, P. K. (2022). Aggregation Behavior of Nitrilotriacetamide (NTAmide) Ligands in Thorium(IV) Extraction from Acidic Medium: Small-Angle Neutron Scattering, Fourier Transform Infrared, and Theoretical Studies. Langmuir, 38(48), 14745-14759. https://doi.org/10.1021/acs.langmuir.2c02394

Karak, A., Mahanty, B., Mohapatra, P. K. , Egberink, R. J. M., Valsala, T. P., Sathe, D. B., Bhatt, R. B. , Huskens, J. , & Verboom, W. (2022). Liquid–Liquid Extraction of Actinides from Nitric Acid Feeds Using Two Hexa-n-alkylnitrilotriacetamides. Solvent extraction and ion exchange, 40(4), 366-386. https://doi.org/10.1080/07366299.2021.1946999

Verma, P. K., Gujar, R. B., Ansari, S. A., Musharaf Ali, S. , J. M. Egberink, R. , Huskens, J. , Verboom, W., & Mohapatra, P. K. (2022). Sequestration of Am³⁺ and Eu³⁺ into ionic liquid containing Aza-macrocycle based multiple-diglycolamide ligands: Extraction, complexation, luminescence and DFT studies. Journal of molecular liquids, 347, [118291]. https://doi.org/10.1016/j.molliq.2021.118291

Distler, P., Mindova, M., Sebesta, J., Gruner, B., Bavol, D. , Egberink, R. J. M. , Verboom, W., Babain, V. A., & John, J. (2021). Stability of different BTBP and BTPhen extracting or masking compounds against γ radiation. ACS Omega, 6(40), 26416-26427. https://doi.org/10.1021/acsomega.1c03678

Mahanty, B., Karak, A., Mohapatra, P. K. , Egberink, R. J. M., Valsala, T. P., Sathe, D. B., Bhatt, R. B. , Huskens, J. , & Verboom, W. (2021). Carrier mediated transport of actinides using hexa–n-hexylnitrilotriacetamide (HHNTA). Chemical Engineering and Processing - Process Intensification, 161, [108323]. https://doi.org/10.1016/j.cep.2021.108323

Banerjee, P., Ansari, S. A., Mohapatra, P. K. , Egberink, R. J. M., Ramasubramanium, S., Patil, C. B. , Huskens, J. , & Verboom, W. (2021). Highly efficient europium(III) uptake with an extraction chromatographic resin containing a unique multiple diglycolamide ligand with a tetraaza-12-crown-4 scaffold. Industrial & engineering chemistry research, 60(6), 2613-2624. https://doi.org/10.1021/acs.iecr.1c00186

Banerjee, P., Ansari, S. A., Mohapatra, P. K. , Egberink, R. J. M., Valsala, T. P., Sathe, D. B., Bhatt, R. B. , Huskens, J. , & Verboom, W. (2021). Highly efficient plutonium scavenging by an extraction chromatography resin containing a tetraaza-12-crown-4 ligand tethered with four diglycolamide pendent arms. Journal of chromatography A, 1653, [462419]. https://doi.org/10.1016/j.chroma.2021.462419

Karak, A., Mahanty, B., Mohapatra, P. K. , J. M. Egberink, R., Valsala, T. P., Sathe, D. B., Bhatt, R. B. , Huskens, J. , & Verboom, W. (2021). Highly efficient and selective extraction of Pu(IV) using two alkyl-substituted amides of nitrilo triacetic acid from nitric acid solutions. Separation and purification technology, 279, [119584]. https://doi.org/10.1016/j.seppur.2021.119584

Bhattacharyya, A., Mohapatra, P. K., Kanekar, A. S., Dai, K. , Egberink, R. J. M. , Huskens, J. , & Verboom, W. (2020). Combined Experimental and Density Functional Theoretical Studies of Am³⁺ and Eu³⁺ Extraction and Complexation with Different Nitrilotriacetamide (NTA) Derivatives. ChemistrySelect, 5(11), 3374-3384. https://doi.org/10.1002/slct.201904393

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202100249 - Organic & Bio-organic Chemistry

+31534895718

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r.j.m.egberink@utwente.nl

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University of Twente
Faculty of Science and Technology
Carré (building no. 15), room C4209
Hallenweg 23
7522NH Enschede
The Netherlands

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University of Twente
Faculty of Science and Technology
Carré C4209
P.O. Box 217
7500 AE Enschede
The Netherlands

Faculty of Science and Technology (TNW), Molecular Nanofabrication (MNF)

University of Twente Drienerlolaan 5
7522 NB Enschede

+31 (0)53 489 9111
info@utwente.nl
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